Zr-MOF-808@MCM-41 catalyzed phosgene-free synthesis of polyurethane precursors

Photodecomposition of Water Catalyzed by Zr- and Ti-MCM-41

Highly efficient multicomponent Biginelli’s synthesis of 3,4-dihydropyrimidin-2(1H)-ones catalyzed by Al-MCM-41 under solvent-free conditions

In this study, an efficient and green process for the synthesis of dihydropyrimidin-2(1H)-ones from aromatic benzaldehydes, ethyl acetoacetate and urea using Al-MCM-41 as heterogeneous catalyst and microreactor under solvent-free conditions has been developed. The advantages of this method are easy work-up procedure, regeneration of the catalyst, clean and neutral reaction conditions.

Highly efficient multicomponent Biginelli’s synthesis of 3,4-dihydropyrimidin-2(1H)-ones catalyzed by Al-MCM-41 under solvent-free conditions

In this study, an efficient and green process for the synthesis of dihydropyrimidin-2(1H)-ones from aromatic benzaldehydes, ethyl acetoacetate and urea using Al-MCM-41 as heterogeneous catalyst and microreactor under solvent-free conditions has been developed. The advantages of this method are easy work-up procedure, regeneration of the catalyst, clean and neutral reaction conditions.

CuCl2 Catalyzed Solvent-free One Pot Synthesis of Dihydropyrimidinones

Spectral and dynamical properties of a Zr-based MOF.

We report on the spectra and dynamics of a Zr-naphthalene dicarboxylic acid (Zr-NDC) MOF in different diluted solvent suspensions and in a concentrated tetrahydrofuran (THF) one. In a diluted diethyl ether (DE) suspension, we observed intraparticle excimer formation between neighboring naphthalene organic linkers, leading to a red-shifted broad band in the emission spectrum and to a dynamics co...